1,4-Butanediol

    • Product Name: 1,4-Butanediol
    • Chemical Name (IUPAC): butane-1,4-diol
    • CAS No.: 110-63-4
    • Chemical Formula: C4H10O2
    • Form/Physical State: Liquid
    • Factroy Site: Yizheng, Yangzhou, Jiangsu China
    • Price Inquiry: sales4@ascent-chem.com
    • Manufacturer: SINOPEC Yizheng Chemical Fibre Company Limited
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    Specifications

    HS Code

    104495

    Cas Number 110-63-4
    Molecular Formula C4H10O2
    Molar Mass 90.12 g/mol
    Appearance Colorless, oily liquid
    Odor Practically odorless
    Melting Point 20.1 °C
    Boiling Point 230 °C
    Density 1.017 g/cm³ (at 20°C)
    Solubility In Water Miscible
    Flash Point 121 °C (closed cup)
    Vapor Pressure 0.03 mmHg (at 20°C)
    Refractive Index 1.446 (at 20°C)
    Viscosity 75 mPa·s (at 20°C)
    Ph 6.0–7.5 (100 g/L in H2O at 20°C)
    Logp Octanol Water -0.96

    As an accredited 1,4-Butanediol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,4-Butanediol is packaged in a 25-liter blue HDPE drum with a secure screw cap, labeled with safety information.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for 1,4-Butanediol involves safely packaging and transporting bulk liquid in drums or IBCs within a 20-foot container.
    Shipping 1,4-Butanediol is shipped in tightly sealed, corrosion-resistant containers, such as drums or intermediate bulk containers. It should be transported as a stable, non-hazardous liquid but requires protection from moisture and contaminants. Proper labeling and documentation are essential, and shipping must comply with local regulations to ensure safe handling and storage.
    Storage 1,4-Butanediol should be stored in tightly sealed containers made of compatible materials, away from heat, sparks, and open flames. Store in a cool, dry, well-ventilated area, protected from direct sunlight and moisture. Keep away from strong oxidizers and acids. Ensure containers are clearly labeled, and implement appropriate spill containment measures. Regularly inspect for leaks or deterioration.
    Shelf Life 1,4-Butanediol typically has a shelf life of about 2 years when stored in tightly sealed containers under cool, dry conditions.
    Application of 1,4-Butanediol

    Applications of 1,4-Butanediol in Industrial Manufacturing

    1,4-Butanediol serves as a fundamental chemical intermediate in a range of high-volume industrial applications. Working directly with large-scale manufacturers, we deliver consistent quality that meets strict compliance standards for downstream synthesis processes. Below, we highlight the primary sectors where this raw material demonstrates critical value in the production chain, describing its specific integration, regulatory context, formulation ratios, and the resulting end products.

    1. Polybutylene Terephthalate (PBT) Resin Synthesis

    Polybutylene terephthalate manufacturers rely on high-purity feedstock to ensure reliable polymerization and mechanical performance in engineering plastics. As a direct precursor in esterification with terephthalic acid or dimethyl terephthalate, material purity and analytical controls remain central throughout production. Maintaining regulated input ratios supports robust mechanical, electrical, and chemical resistance properties for automotive and electronics components.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • UL 94 Flammability Rating for Final Plastics
    • RoHS Directive (EU) 2011/65 for Electronics
    • REACH Registration (EC No. 1907/2006)

    Typical usage ratio

    • 42–46% by weight relative to pure terephthalic acid in resin synthesis; adjusted based on targeted intrinsic viscosity and polymer chain length requirements

    Downstream process integration

    • Charged into esterification reactors at controlled temperature and vacuum immediately following terephthalic acid feed; progress monitored by acid value reduction and distillation output

    Final product types

    • PBT pellets and compounds for injection molding
    • Unfilled and reinforced PBT automotive connectors
    • Electrical insulation components and appliance housings

    2. Tetrahydrofuran (THF) Production

    The manufacture of tetrahydrofuran incorporates catalytic dehydrogenation or dehydration of the diol as the primary process route. Industrial-grade continuous flow systems require consistent quality and feedstock purity to achieve maximum yield and catalyst longevity. Downstream, THF supports applications in polymer synthesis and specialty solvents, subject to meticulous handling and hazard classification protocols.

    Industry compliance standards

    • ISO 14001:2015 Environmental Management
    • OSHA 29 CFR 1910.119 Process Safety Management (for THF plants)
    • REACH Substance Registration and SVHC Risk Assessments
    • ECHA (European Chemicals Agency) guidelines for solvent recovery

    Typical usage ratio

    • Direct 100% as process feed in continuous reactors; feed rate governed by targeted batch quantities and catalyst throughput

    Downstream process integration

    • Introduced into vapor-phase catalytic reactors, passing over alumina or palladium-based catalyst beds; monitored for conversion efficiency and minimized byproduct formation

    Final product types

    • Tetrahydrofuran solvent for polyether production
    • THF solvent blends for PVC and engineering adhesives
    • High-purity THF for pharmaceutical-grade syntheses

    3. Polyurethane Elastomers and Thermoplastic Polyurethanes (TPU)

    Producers of polyurethane elastomers and TPU utilize 1,4-butanediol as a chain extender and soft segment building block, essential for defining elasticity, mechanical strength, and processability of final polymer materials. Dosage and reactivity are tightly controlled to meet demanding specifications for footwear, cable sheathing, and industrial belts, in accordance with precise formulation and safety documentation.

    Industry compliance standards

    • ISO 9001:2015 and ISO 14001:2015 Certification
    • EU Regulation No. 10/2011 for Food Contact Plastics (where applicable)
    • EN 71-3 Toy Safety Standard – Migration of Certain Elements
    • ISO 4589-2 Oxygen Index Testing for Flame Resistance

    Typical usage ratio

    • 15–40% by weight relative to diisocyanate content in polyurethane formulations, fine-tuned for desired hardness and elongation properties

    Downstream process integration

    • Added to reactor or mixing unit as a chain extender following prepolymer (polyol + diisocyanate) synthesis; ratio and sequence define segment architecture and flow behavior

    Final product types

    • Footwear soles and high-abrasion industrial belts
    • Thermoplastic polyurethane granules for extrusion and molding
    • Cable and wire insulation sheathing for automotive and electronics

    4. Gamma-Butyrolactone (GBL) Synthesis

    Gamma-butyrolactone manufacturers employ a catalytic oxidation process, transforming purified 1,4-butanediol in fixed-bed or liquid-phase reactors. Feed quality and process conditions directly impact the color, purity, and stability of the final lactone, influencing downstream use in electronic cleaning, polymer intermediates, and specialty solvents. All process operations adhere to environmental, occupational, and chemical safety directives.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • REACH Registration for GBL and Intermediates
    • Chemical Facility Anti-Terrorism Standards (CFATS), US DHS for Precursors
    • Global Harmonized System (GHS) Labeling and Handling Protocols

    Typical usage ratio

    • 98–100% as main reactor feed; throughput determined by capacity planning and conversion target per batch

    Downstream process integration

    • Direct feed to catalytic reactor for partial oxidation; inlet feed requires water removal and purity checks to limit byproduct formation during conversion to GBL

    Final product types

    • GBL solvent for electronics and battery electrolytes
    • Intermediates for herbicide or pharmaceuticals synthesis
    • Polyvinylpyrrolidone (PVP) precursor in specialty polymers

    5. Polyurethane Rigid Foam Systems

    Manufacturers of rigid polyurethane foams utilize controlled quantities of 1,4-butanediol as a bifunctional crosslinker in panel insulation, appliance, and construction-grade formulations. The controlled introduction after prepolyol or polyisocyanurate blending influences the closed-cell structure, dimensional stability, and flame retardancy of the final insulation product, with all process and formulation parameters falling under strict building safety standards.

    Industry compliance standards

    • EN 13165:2012+A2:2016 for Rigid Foam Thermal Insulating Panels
    • ASTM E84 Surface Burning Characteristics
    • ISO 9001:2015 Quality Management
    • European Directive 89/106/EEC Construction Product Regulation (CPR)

    Typical usage ratio

    • 2–8% by weight of polyol component; varied to optimize reactivity, foam density, and cell size as dictated by end-use insulation needs

    Downstream process integration

    • Dosed into polyol side prior to mixing with isocyanate in high-pressure foam machines; formulation adjustments based on ambient temperature and expansion profile

    Final product types

    • Rigid foam panels for building and vehicle insulation
    • Refrigerator liner foam and appliance insulation blocks
    • Composite insulation systems for industrial refrigeration

    6. Spandex (Elastane) Fiber Production

    High-elasticity spandex manufacturers incorporate controlled dosages to define segmental mobility and stress recovery in spun fibers. The diol acts as a chain extender during prepolymer synthesis, impacting the molecular configuration and microphase separation essential for textile-grade stretch properties, colorfastness, and wash durability across finished garment lines.

    Industry compliance standards

    • Oeko-Tex Standard 100 product class for textile safety
    • ISO 9001:2015 Quality Management for Fiber Manufacturing
    • REACH Regulation for Fiber Chemicals
    • ZDHC (Zero Discharge of Hazardous Chemicals) Process Protocols

    Typical usage ratio

    • 18–24% by weight in polyurethane soft segment for spandex; adjusted for target denier and mechanical performance

    Downstream process integration

    • Blended with macrodiol and diisocyanate to form polymer prepolymer; introduced prior to dry spinning or wet spinning stages for direct fiber formation

    Final product types

    • Elastane (spandex) yarns for woven and knitted sportswear
    • Stretch denim and activewear fabrics
    • Compression garments and hosiery

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    Certification & Compliance
    More Introduction

    1,4-Butanediol: Backbone of Modern Manufacturing

    Understanding 1,4-Butanediol from the Manufacturer’s Perspective

    As a chemical manufacturer focusing on 1,4-Butanediol, we see beyond the technical sheets and transactional exchanges. Instead, we live among the drums, pipelines, and vessels where this essential material takes shape. Through years of hands-on production and direct feedback from downstream users, we’ve developed a practical view of this compound’s impact on industry and everyday products.

    Model and Specifications: What Sets Our 1,4-Butanediol Apart

    Manufacturing 1,4-Butanediol means controlling purity, consistency, and batch traceability at every step. We prioritize product grades that specify moisture content, appearance, and concentration. Our primary offering remains industrial-grade 1,4-Butanediol with a purity of no less than 99.5%. We maintain water content below 0.05% and limit key impurities like gamma-butyrolactone to levels consistently below industry thresholds. This approach has reduced off-spec incidents and product returns for our customers, especially in sectors requiring repeatable performance.

    Rigorous sampling, in-process analytics, and finished product audits are standards set through internal audits and customer feedback. Tanks, transfer lines, and packaging conditions receive regular monitoring for temperature shifts, contamination risks, and seal integrity. All outgoing containers carry batch trace information, not only to meet regulatory requirements but because we’ve seen how vital rapid traceability is in real-world troubleshooting.

    We always ship 1,4-Butanediol in stainless steel drums and ISO tanks to control oxygen exposure and prevent material degradation. Shipments pass through both gas chromatography and Karl Fischer titration checks. These in-house steps make a difference for our formulation and polymer partners whose production lines rely on consistent chemical quality.

    Why 1,4-Butanediol Matters Across Industries

    Every work shift reveals new examples of how 1,4-Butanediol feeds manufacturing sectors you see every day. One of the most immediate uses remains as a precursor for polybutylene terephthalate. Our longstanding partners in the automotive and electronics industries turn to our 1,4-Butanediol to make thermoplastic resins for everything from ignition system casings to appliance housings. The demand for lightweight, heat-resistant plastics roots itself in 1,4-Butanediol chemistry, a connection frequently overlooked at the consumer end.

    We also supply 1,4-Butanediol to elastomer manufacturers. Polyurethane flexibility—used in insulation, midsoles, and industrial gaskets—depends on resilient raw material. Over years of collaboration, we’ve observed how even minimal variations in diol purity affect final polymer stretch and tensile strength. Responsible manufacturers do not tolerate random raw material shifts, so every batch undergoes close property tracking. This insistence on narrow process windows prevents excess waste for end-users and reduces our own reprocessing loads.

    Solvent companies form another pillar of our customer base. From seasoned ink blending plants to upstart coatings operations, each relies on 1,4-Butanediol for its controlled solvency. Its slow evaporation and low odor help produce stable, manageable working environments. We’ve run joint tests on humidity control and surface finish—confirming that our spec-driven manufacturing pays off during drying cycles and with pigment dispersion. Over time, this translates into better user experiences down the chain, from graphic designers to automotive painters.

    Even in the pharmaceutical industry, where raw material scrutiny rises, 1,4-Butanediol finds a home. Though all pharmaceutical-grade rounds undergo additional purification and documentation, the experience we’ve gained from industrial batches anchors our ability to handle high-purity requests. Familiarity with cross-contamination risks, cleanroom production protocols, and unbroken cold-chain logistics helps us adapt to specialty requirements. Many of our lifetime clients, starting in industrial polymers, have grown alongside us to venture into regulated healthcare fields—always depending on our ability to tune production methods.

    Comparing 1,4-Butanediol to Other Related Chemicals

    From a manufacturing floor viewpoint, actual differences between 1,4-Butanediol and similar small glycols or diols reveal themselves in behavior, not marketing copy. Unlike ethylene glycol or propylene glycol, 1,4-Butanediol offers a unique balance of reactivity for polyester and polyurethane synthesis. Its longer carbon chain and secondary alcohol groups create stronger and more temperature-resistant polymers, which is why engineers and chemists keep returning to it for demanding mechanical parts.

    Another close cousin, 1,3-butanediol, carries two hydroxyl groups separated by just one methylene unit. This seemingly minor difference changes everything for the polymer chemist. 1,4-Butanediol’s symmetrical structure allows for greater flexibility and more regular incorporation into polymer chains, directly impacting product toughness, elongation, and heat resistance. Decades of feedback have taught us that substituting one for the other almost never yields equivalent performance, no matter how similar their chemical profiles might look on a table.

    Even when compared to shorter-chain options such as diethylene glycol, we see that 1,4-Butanediol’s volatility and reactivity set it apart in practical use. Its slightly higher boiling point and cleaner degradation pathways mean faster batch cycles and less risk of equipment fouling. In our own maintenance records, lines processing 1,4-Butanediol accumulate residues at a much slower rate, saving work hours and materials needed for regular cleaning cycles.

    Supporting Claims with Experience: Quality in the Details

    Over time, product quality has become more about real-life performance than numbers on a quality sheet. For example, during a particularly humid summer, one facility’s finished polymer beads began to soften unexpectedly. Detailed moisture analysis at our plant traced a minor spike in water content—well within marketing literature tolerances but above threshold for our customer’s extruder settings. Working with both their line engineers and our QA, we tightened water checks for incoming production orders. Since then, both our failure rates dropped, and the customer has trusted us for more demanding applications.

    Batch consistency also affects transport and storage handling. Customers storing 1,4-Butanediol outdoors in variable climates soon notice that lower-grade material tends to pick up coloring and slight odors. This results in additional screening steps before use. By implementing a closed transfer system and scheduled tank inspections, we drastically reduced air contact and off-flavor issues. Complaints dropped, and clients chose to stay with our material. There’s a cost to running a tighter ship, but we’ve found the returns—in both reputation and order frequency—far outweigh raw material savings.

    Within our own facility, small decisions such as prioritizing fresh nitrogen blanketing over re-using recovered process gases have shown up in order quality. We caught early-stage oxidation of a few large batches and prevented out-of-spec shipments by switching to a stricter protocol. It’s not just about ticking off quality boxes; it’s about understanding how a single slip-up can propagate downstream. Too many years spent untangling end-customer complaints to take short cuts such as that.

    Environmental Responsibility and Product Lifecycle

    Commitment to environmental impact drives many of our investments in process control and waste minimization. 1,4-Butanediol manufacturing, traditionally anchored in petrochemistry, produces effluents and byproducts that can strain local systems. Over the past decade, most of our capital expenditure has gone into scrubbers, closed-loop cooling, and recycling of wash waters. Lowering microfiber discharge and capturing fugitive vapors takes daily vigilance, not just periodic inspections.

    Many buyers ask about bio-based routes for 1,4-Butanediol. We track developments in this area closely, from fermentation methods to hybrid catalytic processes. Yet scaling these alternatives to industrial levels requires more than technical feasibility. Consistent feedstock supply, energy management, and product purity matching are hurdles in practice. We collaborate with process developers, conduct pilot-scale runs, and transparently share pilot quality data with partners interested in renewables. The conversation about greener chemistry only moves forward when both performance and cost stabilize—something we’ve realized only comes with persistent investment and honesty about technical tradeoffs.

    Packaged 1,4-Butanediol poses its own end-of-life questions. Some customers have transitioned from steel to composite containers to lighten shipping loads, but disposal and reusability remain points of debate. In our own logistics, we’ve initiated drum recovery programs, encourage partners to return empties, and route washed containers to certified recyclers. Beyond compliance, these programs prove popular with customers interested in reducing their own environmental liabilities.

    Challenges in the Field and Practical Solutions

    Manufacturers deal with operational swings, transportation mishaps, and market fluctuations in global feedstocks. These realities make every shipment a logistical exercise. Several years back, a rail delay in delivering hydrogen feedstock nearly halted BDO synthesis for a full week. Quick sourcing from neighboring plants, along with batch scheduling flexibility, allowed us to fulfill priority contract shipments. Such lessons cemented the need for diversified suppliers and contingency planning. Today, our logistics teams maintain live status feeds and emergency procurement protocols for all critical inputs, helping us avoid production crunches.

    Long-term relationships with downstream users push us toward continuous improvement. Our polyurethane partners often request tweaks in BDO content or tighter impurity levels for specialty batches designed for new foam grades. Instead of offering one-size-fits-all specs, we keep several pilot lines running specifically to trial customer-driven modifications. These small-batch runs keep our technical team close to evolving customer needs, letting issues surface before they show up in commercial-scale shipments.

    Batch traceability comes up regularly during audits or recalls, especially with large-scale downstream conversion. Investments in digital batch tracking software now give customers immediate access to production history. During a recent recall affecting several drum lots, the speed at which we delivered batch genealogy helped our partners isolate and remove affected products quickly, reducing their own exposure and the risk of reputational loss.

    Global shipping regulations and customs documentation create additional hurdles. International customers often struggle with import clearance delays due to shifting hazardous materials definitions. We stay updated on region-specific rules and help equip our clients with the necessary safety and transport paperwork, minimizing time lost at borders. Feedback from months where documentation lagged led us to overhaul our export paperwork workflow and cross-train more staff on global requirements.

    Listening to Customers: Building Quality from the Factory Outward

    The most useful feedback comes from people who work hands-on with our material. Processing teams describe how small shifts in impurity levels can cause agitation, poor mixing, or even unplanned downtime. By investing time and resources into regular site visits and technical support, we’ve gotten to know the realities of our product’s performance in a range of uses. Joint testing protocols have proven essential—both for product improvement and confidence building.

    When handling concerns such as packaging leaks or suspected contamination, direct dialogue works better than written procedures. We rotate experienced production supervisors through our technical support desk, so insights from the plant floor reach customers directly. Sharing best practices helps end-users solve problems faster, reduces complaint turnaround, and brings solutions that work for real-world applications.

    For one adhesive manufacturer, our team set up on-site blending trials to measure how minor shifts in amine impurities impacted final adhesive tack and curing rate. Adjustments to our raw material screening based on those early results helped both parties; the customer achieved more consistent curing, and our yield loss from rejected drums dropped. These shared wins come from a practical, transparent approach to problem-solving.

    Innovation and the Future of 1,4-Butanediol Manufacturing

    Demand for high-performance polymers and specialty solvents only intensifies. Research teams are exploring novel applications for 1,4-Butanediol, from next-generation bioplastics to advanced heat-resistant materials. We field regular requests from universities and research consortia for batch samples and technical data. Providing technical support for pilot trials and exploring modifications for higher-purity fractions pushes us to continually improve process technology.

    Automation and data analytics enter the picture as well. Equipment upgrades—such as in-line gas chromatography and advanced purification skid controls—have improved reproducibility, raised throughput, and reduced energy costs. Comparing current plant incident logs with those from ten years ago, we see fewer off-spec deliveries, a tighter range on key purity metrics, and a marked drop in batch-to-batch variability. These process improvements translate into stronger customer trust and more stable long-term supply relationships.

    As regulations shift, and sustainable chemistry gains more attention, we continue to test new manufacturing routes. Fermentation pathways and hybrid bio-catalytic methods, once considered uneconomical, now enter commercial trials. Sourcing agricultural feedstocks reliably and ensuring they match the impurity profile of petrochemical-derived product remains a challenge. Our role as a chemical manufacturer involves honest, direct feedback to customers about the real-world feasibility of “green” alternatives. Our experience tells us that collaboration, not marketing, drives lasting progress.

    Conclusion: Experience Shapes How We Manufacture 1,4-Butanediol

    Years of producing, shipping, and supporting 1,4-Butanediol have shown that performance on the factory floor matters most. From polyesters to polyurethanes and specialty solvents, small decisions around purity, packaging, and traceability ripple outward. Industry shifts toward greener and more efficient production rely on shared knowledge and a willingness to invest in long-term solutions. By working closely with technical teams and end-users, we find practical answers to challenges while keeping product quality, safety, and sustainability at the core of what we do.